Characterization of dynamic behavior of a spout-fluid bed with Shannon entropy analysis

Differential pressure fluctuation time series were obtained at different locations in a two-dimensional spout-fluid bed with a cross section of 300 × 30 mm and height 2000 mm. Shannon entropy analysis of differential pressure fluctuations was developed to characterize the dynamic behavior. Effects of two important operating parameters (spouting gas velocity and fluidizing gas flow rate) on the Shannon entropy were examined. It was demonstrated that a spout-fluid bed at a high spouting gas velocity or fluidizing gas flow rate was a deterministic chaos system since the Shannon entropies at all bed locations increased sharply and asymmetric unstable flows occurred. Shannon entropies were found to be significantly different at various bed locations. Shannon entropies of different flow regimes were distinct, so they were used to identify the flow regimes. The results show that the Shannon entropy helps to grasp the complex characteristics of dynamic behavior in spout-fluid beds.     

河流工程中的图形绘制与处理

在河流工程领域,不管是实体模型还是数学模型,对多样化的数据和丰富多彩的图形的需要越来越强烈,旧的表现形式已经被层出不穷的新的、信息量大而且地位高的2D、3D图形所取代,因此在工程中合理地选择绘图方式和开发软件就变得十分重要。以实际操作经验为基础,从基本操作类到二次开发类再到高端图形图像开发类,详细地讨论了在河流工程中各种图形的绘制和处理方法选择,具有一定参照价值。     

2,4,6‐Trichlorophenol and phenol removal in methanogenic and partially‐aerated methanogenic conditions in a fluidized bed bioreactor

A fluidized bed bioreactor (FBBR) was operated for more than 575 days to remove 2,4,6‐trichlorophenol (TCP) and phenol (Phe) from a synthetic toxic wastewater containing 80 mg L^?1 of TCP and 20 mg L^?1 of Phe under two regimes: Methanogenic (M) and Partially‐Aerated Methanogenic (PAM). The mesophilic, laboratory‐scale FBBR consisted of a glass column (3 L capacity) loaded with 1 L of 1 mm diameter granular activated carbon colonized by an anaerobic consortium. Sucrose (1 g COD L^?1) was used as co‐substrate in the two conditions. The hydraulic residence time was kept constant at 1 day. Both conditions showed similar TCP and Phe removal (99.9 + %); nevertheless, in the Methanogenic regime, the accumulation of 4‐chlorophenol (4CP) up to 16 mg L^?1 and phenol up to 4 mg L^?1 was observed, whereas in PAM conditions 4CP and other intermediates were not detected. The specific methanogenic activity of biomass decreased from 1.01 ± 0.14 in M conditions to 0.19 ± 0.06 mmolCH₄ h^?1 gTKN^?1 in PAM conditions whereas the specific oxygen uptake rate increased from 0.039 ± 0.008 in M conditions to 0.054 ± 0.012 mmolO₂ h^?1 gTKN^?1, which suggested the co‐existence of both methanogenic archaea and aerobic bacteria in the undefined consortium. The advantage of the PAM condition over the M regime is that it provides for the thorough removal of less‐substituted chlorophenols produced by the reductive dehalogenation of TCP rather than the removal of the parent compound itself. Copyright © 2005 Society of Chemical Industry     

Ozonation of CI Reactive Black 5 using rotating packed bed and stirred tank reactor

This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry     

河口水流、波浪、潮流、泥沙、河床变形二维数学模型

根据河口“波浪掀沙，潮流输沙”的泥沙运动机制，引入“波浪幅射应力”反应波浪对水体和泥沙的驱动力．考虑波浪对底部泥沙作用力、波浪对水流挟沙能力的影响及风场对水流和泥沙运动的影响．同时考虑泥沙粒径大小、水体含盐度、含沙量及水流紊动程度等因素对絮凝沉速的影响．用ＡＤＩ算法求解沿水深平均方程，破开算子法解悬移质不平衡输沙方程及河床变形方程，引入通度概念处理岸滩不规则边界，建立河口水流、波浪、潮流、泥沙、河床变形二维数学模型．通过实测资料及卫星摇感图像对所建数学模型进行检验，表明它可以较好地预测河口泥沙的运动     

泥沙输移矢量式及其应用

本文基于Parker等人泥沙输移矢量式的分析和研究，增加了上举力的作用，并考虑了泥沙颗粒受力非平衡条件，采用牛顿力学的矢量分析法，推导了泥沙输移的通用矢量式。经对公式简化，且用Ikeda和笔者试验资料的验证，证明计算值与试验值吻合较好。     

用高程与河道断面特性平均积分曲线图解河道水面线

从恒定、渐变流河段能量方程式中推导出以高程与河道断面特性平均积分曲线图解河道水面线的方法,并通过某河段水面线计算实例说明了此方法的计算图解步骤。对于同一河道,由于高程与河道断面特性平均积分曲线不变。故曲线可重复利用。因此,对进行多种设计标准的水面线计算可很方便地直接从曲线图上得出水面线结果。     

Kinetic study of the hydrolysis of isocyanic acid in the gas phase

The hydrolysis of isocyanic acid in the gaseous phase has been investigated at temperatures between 553 and 613 K by mass spectrometry and evaluated to obtain the corresponding kinetic data. The reaction order and reaction constant have been determined. Finally, the influence of water on the catalysed formation of melamine from isocyanic acid under the operating conditions employed has been investigated in order to determine whether there is a need to try the process gas.     

河道溃堤与溃堤波的一、二维耦合计算数值模拟

建立了一维河道溃堤与二维溃堤波耦合计算的水力模型、其中，河道的计算采用一维明渠非恒定流Saint—Venant方程组，求解的过程与溃口的数值模拟耦合；溃堤按渐溃计算，将溃口模拟为梯形，随时间线性增大；溃堤波的计算采用在有限体积无结构网格上建立的TVD—MUSCL格式．模拟算例表明，建立的河道溃堤与溃堤波的一、二维耦合计算水力模型模拟结果比较接近真实溃堤过程．     

抚河流域水生态环境恢复措施初探

简述江西省抚河流域的概况、水生态环境的现状及存在的问题.包括淤泥的堆积、水土的流失、水污染、沿岸圩堤的防洪标准普遍偏低等.并对这些问题提出了流域水生态环境恢复的目标,针对抚河流域水生态环境的恢复目标提出了水权分配、水土保持治理、水工程治理、水质治理等方面的一系列初步的措施与建议.